Because Phylacteries have intrinsic holiness, items which function with them are considered items which serve holiness, and they may not be disposed of. Instead, they are buried: Megillah 26b
The normal manner of wearing phylacteries is to wear one pair, not multiple pairs: Eruvin 95b
Conditions
Phylacteries require a "Clean Body": Shabbat 130a
Definition of the requisite "Clean Body": Shabbat 130a
Urinating while wearing Phylacteries: Berachot 23a-b; Succah 41b
Concern for passing gas while wearing phylacteries: Berachot 23a